WebGeneral mechanism. The chain mechanism is as follows, using the chlorination of methane as a usual example: . 1. Initiation: Splitting or homolysis of a chlorine molecule to form two chlorine atoms, initiated by ultraviolet radiation.A chlorine atom has an unpaired electron and acts as a free radical. 2. WebSide chain chlorinations of aromatic compounds are usually carried out above 80° C. This is because lower temperatures are conducive to nuclear chlorination and it is more difficult to sustain free radical chain reactions at lower temperatures. However, when the resulting chlorinated products are thermally unstable, a problem results.

US4719298A - Side chain chlorination process of heterocycles

WebSide-Chain Chlorination of Toluene. Benzyl chloride, used mainly in the manufacture of plasticizers, may be prepared by the thermal or photochemical chlorination of toluene.191,192 In the thermal process chlorine is passed through toluene at 65-100°C. To minimize the formation of benzal chloride and benzotrichloride, the conversion is limited ... WebThe reaction mixture in the reaction zone in contact with adsorbent carbon is maintained at conditions conducive to chlorination of the ethyl side-chain of the ethylpolychlorobenzene … thin cut beef steak recipe

Applications of N -Chlorosuccinimide in Organic Synthesis

WebThe final product obtained, when toluene is subjected to side chain chlorination followed by hydrolysis at 373 K is benzaldehyde. Side chain chlorination of toluene gives … WebStep 2: Propagation. The next two steps in the mechanism are called propagation steps. In the first propagation step, a chlorine radical abstracts hydrogen atom from methane. This … Web1 Introduction Side-chain chlorinated species are important precursors for the production of a manifold of chemical compounds e.g. benzyl alcohol, benzyl butyl phthalate, … thin cut beef top round steak recipes